To use the program, you first need to assemble it with the assembler found in pv2devkit. Then you run the resulting pv2 file with the "Run PV2 Code" button in pv2tool.
If you define DATA0 as $08 then you will use the right side (toward the battery) of the power LED which is labeled D8. I have not tried it yet, but you may be able to connect an LED or solar cell to an amplifier and receive the audio wirelessly from the power LED. The range would probably very low unless you replaced your power LED with a brighter one.
On one of my cameras I have removed the flash circuitry and so I found it more convenient to use DATA0 as $40 which is the third pin on the flash/battery header.
I have labeled the two points on the picture below. Note that you will probably not have the -*test*-('") point directly below pin 3 on your camera as shown in the picture.
